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Dissolving alkali metals in zeolites: Genesis of the perfect cluster crystal

Abstract:

The interaction of alkali metals with dehydrated zeolites Y and A leads, in a process which bears many similarities to the dissolution of those metals in non-aqueous liquid solvemts, to the formation of inclusion compounds which may be regarded as ordered arrays of closely spaced clusters, and whose properties are dependent on interactions between the clusters. A combined analysis of electron spin resonance, magnetic susceptibility and powder neutron diffraction results enabled us to follow i...

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Publication status:
Published

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Publisher copy:
10.1039/dt9960000719

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Issue:
5
Pages:
719-727
Publication date:
1996-03-07
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:c59ccfce-3ec5-4ad3-a913-561c637a62a3
Source identifiers:
46656
Local pid:
pubs:46656

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