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The ultraviolet spectrum of the CoCl2 radical, studied at vibrational and rotational resolution

Abstract:

The laser excitation spectrum of the 327 nm band system of CoCl2, formed in a free-jet expansion, has been recorded at a rotational temperature of approximately 10 K. The spectrum is congested and suffers extensive perturbations. A progression in the excited state symmetric stretching vibration has been identified. The decrease in the symmetric stretching vibrational wave number on excitation is considerable [v'1=195.7(12), v''1=358.1(17) cmˉ¹]. Despite widespread perturbations in the rotatio...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1063/1.2188937

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Research group:
Professor John Brown's Research Group
Role:
Author
More by this author
Institution:
Macalester College, St. Paul, Minnesota, USA
Department:
Department of Chemistry
Role:
Author
Publisher:
American Institute of Physics Publisher's website
Journal:
Journal of Chemical Physics Journal website
Volume:
124
Issue:
20
Article number:
204302
Publication date:
2006-05-01
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
Language:
English
Keywords:
Subjects:
UUID:
uuid:c5706092-0327-4362-ab0a-9814aeac0ebc
Local pid:
ora:1741
Deposit date:
2008-03-14

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