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The ultraviolet spectrum of the CoCl2 radical, studied at vibrational and rotational resolution

Abstract:

The laser excitation spectrum of the 327 nm band system of CoCl2, formed in a free-jet expansion, has been recorded at a rotational temperature of approximately 10 K. The spectrum is congested and suffers extensive perturbations. A progression in the excited state symmetric stretching vibration has been identified. The decrease in the symmetric stretching vibrational wave number on excitation is considerable [v'1=195.7(12), v''1=358.1(17) cmˉ¹]. Despite widespread perturbations in the rotatio...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1063/1.2188937

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Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Physical and Theoretical Chemistry Laboratory
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Institution:
University of Oxford
Research group:
Professor John Brown's Research Group
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Physical and Theoretical Chemistry Laboratory
More by this author
Institution:
Macalester College, St. Paul, Minnesota, USA
Department:
Department of Chemistry
Publisher:
American Institute of Physics Publisher's website
Journal:
The Journal of Chemical Physics Journal website
Volume:
124
Issue:
20
Pages:
Article: 204302
Publication date:
2006-05-05
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
URN:
uuid:c5706092-0327-4362-ab0a-9814aeac0ebc
Local pid:
ora:1741

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