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Heterogeneous ECE processes at channel electrodes: Analytical theory. Distinguishing hetero- and homogeneous ECE reactions

Abstract:

Analytical theory is developed for heterogeneous ECE reactions occurring at channel electrodes. Simple expressions are presented that allow the ready mechanistic interpretation of experimental data and the deduction of corresponding rate constants. These are shown to be in excellent agreement with numerical simulations and consistent with experiments conducted on the reduction of nitromethane in buffered aqueous solution at Hg/Cu electrodes deposited on a platinum substrate thought to proceed...

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Publication status:
Published

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Publisher copy:
10.1021/jp9720808

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
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Journal:
JOURNAL OF PHYSICAL CHEMISTRY B
Volume:
102
Issue:
9
Pages:
1515-1521
Publication date:
1998-02-26
DOI:
EISSN:
1520-5207
ISSN:
1089-5647
Source identifiers:
36418
Language:
English
Pubs id:
pubs:36418
UUID:
uuid:c56196f3-8908-4aeb-954d-bdb20fff4aa3
Local pid:
pubs:36418
Deposit date:
2012-12-19

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