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Differential pulse techniques in weakly supported media: Changes in the kinetics and thermodynamics of electrode processes resulting from the supporting electrolyte concentration

Abstract:

Square wave voltammetry (SWV) and differential multipulse voltammetry (DMPV) in weakly supported media are investigated. The numerical simulation procedures reported in literature (Streeter et al., J. Phys. Chem. C 112 (2008) 13716-13728; Limon-Petersen et al., J. Phys. Chem. C 114 (2010) 2227-2236) for electrochemical experiments in low conductivity solutions is applied with success. From this theory, the influence of the concentration of supporting electrolyte on the voltammograms is discus...

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Publication status:
Published

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Authors


Barnes, EO More by this author
Laborda, E More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
673
Pages:
13-23
Publication date:
2012-05-15
DOI:
ISSN:
1572-6657
URN:
uuid:c535d645-a2d2-4c75-8269-9d9d6229b430
Source identifiers:
329393
Local pid:
pubs:329393

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