- Abstract:
-
The depth of penetration of photolytically generated, gas-phase O( 3P) atoms into thioalkyl self-assembled monolayers (SAMs) has been investigated. Custom-synthesized, site-selectively deuterated SAMs were prepared on Au substrates and characterized by scanning tunneling microscopy (STM). Relative yields of gas-phase OD were detected by laser-induced fluorescence (LIF). Reaction was suppressed at the terminal CD3 by the higher abstraction barriers for primary D atoms, yielding only 16 ± 3% of...
Expand abstract - Publisher copy:
- 10.1021/jz100587g
-
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- Journal:
- Journal of Physical Chemistry Letters
- Volume:
- 1
- Issue:
- 13
- Pages:
- 1917-1921
- Publication date:
- 2010-07-01
- DOI:
- EISSN:
-
1948-7185
- ISSN:
-
1948-7185
- URN:
-
uuid:c51889fb-2b5c-445f-bcab-0c5dc813e00d
- Source identifiers:
-
299766
- Local pid:
- pubs:299766
- Language:
- English
- Copyright date:
- 2010
Journal article
How penetrable are thioalkyl self-assembled monolayers?
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