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Water at an electrochemical interface--a simulation study.

Abstract:

The results of molecular dynamics simulations of the properties of water in an aqueous ionic solution close to an interface with a model metallic electrode are described. In the simulations the electrode behaves as an ideally polarizable hydrophilic metal, supporting image-charge interactions with charged species, and it is maintained at a constant electrical potential with respect to the solution so that the model is a textbook representation of an electrochemical interface through which no ...

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Publication status:
Published

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Publisher copy:
10.1039/b805544k

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
Journal:
Faraday discussions
Volume:
141
Pages:
423-441
Publication date:
2009-01-01
DOI:
EISSN:
1364-5498
ISSN:
1359-6640
Language:
English
Pubs id:
pubs:369754
UUID:
uuid:c51709eb-3d1a-449b-bc9b-61e0b7e6044d
Local pid:
pubs:369754
Source identifiers:
369754
Deposit date:
2013-11-16

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