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Mechanistic studies of hydrocarbon combustion and synthesis on noble metals.

Abstract:
(Figure Presented) Common staging point: Results of DFT studies on surface-catalyzed processes indicate that oxymethylidyne species (CHO) are intermediates in both the combustion and the synthesis of hydrocarbons on noble-metal surfaces (the picture shows CHO formation on Pd). Combustion and synthesis proceed by very similar pathways, but in opposite directions, even though different metals are used in the two processes. © 2008 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200800685

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry
Jenkins, SJ More by this author
Journal:
Angewandte Chemie (International ed. in English)
Volume:
47
Issue:
28
Pages:
5253-5255
Publication date:
2008
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:c4a09480-adf3-46cd-9c4a-28701b79b158
Source identifiers:
258735
Local pid:
pubs:258735

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