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A convenient route to a norbornadiene adduct of iridium with chelating phosphines, [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] and a comparison of reactivity with H2 in solution and the solid-state

Abstract:

The straightforward synthesis of two cationic iridium norbornadiene species bearing simple bidentate phosphines is reported [Ir(R2PCH2CH2PR2)(NBD)][BAr4F] [NBD = norbornadiene; R = tBu, Cy; ArF = 3,5-C6H3(CF3)2]. The hydrogenation of [Ir(tBu2PCH2CH2PtBu2)(NBD)][BAr4F] in the solution phase and in the solid state is described in which saturated (solution) or unsaturated (solid-state) dimeric species with bridging hydrides are formed. The solid-state structures, as determined by single crystal ...

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Publication status:
In press
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1016/j.jorganchem.2015.12.001

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Publisher:
Elsevier Publisher's website
Journal:
Journal of Organometallic Chemistry Journal website
Publication date:
2015-10-12
DOI:
ISSN:
0022-328X
URN:
uuid:c470aea1-552c-426b-9b97-c4a69355d715
Source identifiers:
589983
Local pid:
pubs:589983

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