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REACTIVITY OF NIDO-[2-(FE(ETA-C5H5))B5H10] WITH SOME TRANSITION-METAL HYDRIDE COMPLEXES

Abstract:

The reaction of nido-[2-{Fe(η-C5H5)}B5H10] with [Mo(PMe2Ph)4H4] gave capped-closo-[1-{Fe(η-C5H5)}-2-{Mo(PMe 2Ph)3H}B5H7] which has been characterised by X-ray crystallography as well as by 11B and 1H NMR spectroscopy. The structure determination [monoclinic, space group P21/c, a = 15.586(5), b = 11.523(4), c = 19.186(4) Å, β = 106.23(2)°] reveals a capped-closo geometry with one Fe-Mo-B face being capped by a boron atom and the other having a triply bridging hydrogen atom. The isostructural t...

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Publication status:
Published

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Publisher copy:
10.1039/dt9940003337

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
23
Pages:
3337-3342
Publication date:
1994-12-07
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:c42aae94-0685-492e-869a-be98e7248ad2
Source identifiers:
51325
Local pid:
pubs:51325

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