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VIBRATION-ROTATION SPECTRUM OF THE CARBON-DIOXIDE ACETYLENE VANDERWAALS COMPLEX IN THE 3 MU-REGION

Abstract:

The infrared absorption spectrum of the carbon dioxide-acetylene van der Waals complex has been observed in a pulsed molecular beam. A color center laser was used to excite the vibration associated with the antisymmetric hydrogen stretching mode of the acetylene monomer. The vibrational origin is 3281.740 cm-1 and the rotational constants are A″ = 8876, B″ = 2959, C ″ = 2155, A ′ = 8864, B ′ = 2855, and C′ = 2154 MHz. The axes of the two monomer are parallel to one another and the complex has...

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Publication status:
Published

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Publisher copy:
10.1063/1.455175

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Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
89
Issue:
3
Pages:
1245-1250
Publication date:
1988-08-01
DOI:
ISSN:
0021-9606
URN:
uuid:c2fb4fa3-cefb-4e99-9cef-1b9102e45b7b
Source identifiers:
43018
Local pid:
pubs:43018
Language:
English

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