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Anodic stripping voltammetry at hydrodynamic mercury thin film electrodes. Part 2. Numerical simulation of stripping peaks for irreversible and quasireversible processes

Abstract:

The time dependent backwards implicit method is used to simulate the shape and position of the stripping peaks in DC (linear scan) anodic stripping voltammetry at mercury thin film hydrodynamic electrodes for electrochemically irreversible and quasireversible systems assuming that the electrode diffusion layer thickness is uniform, as in the case of a rotating disk electrode. The effect of the electrochemical rate constant in influencing both the peak potential and peak shape is examined and ...

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Publication status:
Published

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Publisher copy:
10.1002/elan.1140091702

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
ELECTROANALYSIS
Volume:
9
Issue:
17
Pages:
1305-1310
Publication date:
1997-11-05
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
URN:
uuid:c13a4fb1-8f99-440d-80ec-43498f298717
Source identifiers:
36341
Local pid:
pubs:36341

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