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ELECTRIC-FIELD EFFECTS ON ZERO-KINETIC-ENERGY PHOTOELECTRON-SPECTRA - AN EXPLANATION OF OBSERVED TRENDS

Abstract:
An explanation is offered for the propensity for large negative changes of rotational angular momentum in ZEKE photoelectron spectra, which is increasingly observed as the rotational constant of the photoion decreases; Stark mixing becomes progressively more important, facilitating multistep rotational autoionization processes. The Inglis-Teller limit serves as a useful benchmark for assessing the importance of electric field effects. A discussion is presented of the relative importance of l mixing and J mixing. © 1993.
Publication status:
Published

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Journal:
CHEMICAL PHYSICS LETTERS
Volume:
202
Issue:
1-2
Pages:
153-160
Publication date:
1993-01-15
DOI:
ISSN:
0009-2614
URN:
uuid:c114d9df-5e41-4984-a773-d2e3f890e759
Source identifiers:
44056
Local pid:
pubs:44056
Language:
English

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