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Topochemical reduction of the Ruddlesden-Popper phases Sr2Fe(0.5)Ru(0.5)O4 and Sr3(Fe(0.5)Ru(0.5))2O7.

Abstract:

Reaction of the Ruddlesden-Popper phases Sr2Fe(0.5)Ru(0.5)O4 and Sr3(Fe(0.5)Ru(0.5))2O7 with CaH2 results in the topochemical deintercalation of oxide ions from these materials and the formation of samples with average compositions of Sr2Fe(0.5)Ru(0.5)O(3.35) and Sr3(Fe(0.5)Ru(0.5))2O(5.68), respectively. Diffraction data reveal that both the n = 1 and n = 2 samples consist of two-phase mixtures of reduced phases with subtly different oxygen contents. The separation of samples into two phases...

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Publication status:
Published

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Publisher copy:
10.1021/ic400930y

Authors


Denis Romero, F More by this author
Gianolio, D More by this author
Bingham, PA More by this author
d'Hollander, JC More by this author
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Journal:
Inorganic chemistry
Volume:
52
Issue:
19
Pages:
10920-10928
Publication date:
2013-10-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:bf636262-6842-47e5-9a32-a7e99e033bc6
Source identifiers:
429286
Local pid:
pubs:429286
Language:
English

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