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Enantioselective suzuki reactions: catalytic asymmetric synthesis of compounds containing quaternary carbon centers.

Abstract:
Prochiral ditriflates can act as substrates in asymmetric Suzuki couplings by using an enantioselective desymmetrization strategy. The products are obtained with selectivities up to 86% ee and contain a quaternary carbon center and a synthetically useful vinyl triflate functionality (see scheme).
Publication status:
Published

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Publisher copy:
10.1002/anie.200352648

Authors


Willis, MC More by this author
Powell, LH More by this author
Claverie, CK More by this author
Watson, SJ More by this author
Journal:
Angewandte Chemie (International ed. in English)
Volume:
43
Issue:
10
Pages:
1249-1251
Publication date:
2004-02-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:bf4e9b03-d01f-4ee9-8053-a802cbe6d256
Source identifiers:
52461
Local pid:
pubs:52461

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