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Unidirectional photoinduced shuttling in a rotaxane with a symmetric stilbene dumbbell

Abstract:
Up and down the dumbbell: Photoisomerization of a stilbene rotaxane results in relocation of the cyclodextrin macrocycle in just one direction (see scheme). This behavior, and that of related rotaxanes, sheds light on the mechanism of shuttling in molecular machines.
Publication status:
Published

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Authors


Stanier, CA More by this author
Alderman, SJ More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Journal:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume:
41
Issue:
10
Pages:
1769-+
Publication date:
2002
DOI:
ISSN:
1433-7851
URN:
uuid:bf0e2d06-4cd6-4a07-b690-66b5e1e82e18
Source identifiers:
51820
Local pid:
pubs:51820

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