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Unidirectional photoinduced shuttling in a rotaxane with a symmetric stilbene dumbbell

Abstract:
Up and down the dumbbell: Photoisomerization of a stilbene rotaxane results in relocation of the cyclodextrin macrocycle in just one direction (see scheme). This behavior, and that of related rotaxanes, sheds light on the mechanism of shuttling in molecular machines.
Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
Journal:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume:
41
Issue:
10
Pages:
1769-+
Publication date:
2002-01-01
DOI:
ISSN:
1433-7851
URN:
uuid:bf0e2d06-4cd6-4a07-b690-66b5e1e82e18
Source identifiers:
51820
Local pid:
pubs:51820

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