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Oxidation of N,N,N ',N '-tetraalkyl-para-phenylenediamines in a series of room temperature ionic liquids incorporating the bis(trifluoromethylsulfonyl)imide anion

Abstract:

The five room temperature ionic liquids: 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([CnMIM][N(Tf)2], n = 2, 4, 8, 10) and n-hexyltriethylammonium bis(trifluoromethylsulfonyl)imide ([N6222][N(Tf)2]) were investigated as solvents in which to study the electrochemical oxidation of N,N,N′,N′-tetramethyl-para-phenylenediamine (TMPD) and N,N,N′,N′-tetrabutyl-para-phenylenediamine (TBPD), using 20 μl micro-samples under vacuum conditions. The effect of dissolved atmospheric gases...

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Publication status:
Published

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Authors


Klymenko, OV More by this author
Hardacre, C More by this author
Seddon, KR More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
556
Pages:
179-188
Publication date:
2003-09-30
DOI:
ISSN:
0022-0728
URN:
uuid:bebe14bc-e56b-48dd-8237-9db337a59380
Source identifiers:
38836
Local pid:
pubs:38836

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