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A new reactivity pattern for vinyl bromides: cine-substitution via palladium catalysed C-N coupling/Michael addition reactions.

Abstract:
Palladium catalysed C-N bond formation can be used to convert vinyl bromides to the corresponding enamines, which are reacted in situ with alkylidene malonates to provide Michael adducts. The overall transformation results in cine-substitution of the starting vinyl bromide.
Publication status:
Published

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Publisher copy:
10.1039/b508464d

Authors


Willis, MC More by this author
Chauhan, J More by this author
Whittingham, WG More by this author
Journal:
Organic and biomolecular chemistry
Volume:
3
Issue:
17
Pages:
3094-3095
Publication date:
2005-09-05
DOI:
EISSN:
1477-0539
ISSN:
1477-0520
URN:
uuid:bdf8e134-dfc5-4347-a15b-76f742fac17c
Source identifiers:
52466
Local pid:
pubs:52466

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