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Infrared emission from the CF3+NO2 reaction

Abstract:

The reaction of the CF3 radical with NO2 has been investigated by using time-resolved FTIR emission spectroscopy. Strong infrared emission has been attributed to products, CF2O and FNO, excited in the ν2 and ν1 modes, respectively. The direct one-step production pathway 1a is suggested as a major reaction channel: CF3 + NO2 → CF2O + FNO, ΔH°298 = -267 kJ mol-1 (1a); → CF2O + F + NO, ΔH°298 = -31 kJ mol-1 (1b). The rate constant for reaction 1 was measured to be (2.4 ± 0.5) × 10-11 cm3 molecul...

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Publication status:
Published

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Publisher copy:
10.1021/jp962655l

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF PHYSICAL CHEMISTRY A
Volume:
101
Issue:
14
Pages:
2634-2642
Publication date:
1997-04-03
DOI:
EISSN:
1520-5215
ISSN:
1089-5639
URN:
uuid:bd523e5d-cbe2-4b45-aba2-f4723637e406
Source identifiers:
45551
Local pid:
pubs:45551
Language:
English

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