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Synthesis and rac-lactide ring-opening polymerisation studies of new alkaline earth tetrahydroborate complexes.

Abstract:

Reaction of K[HC(C(Me)NAr')(2)] (Ar' = 2,6-C(6)H(3)(i)Pr(2)) with Mg(BH(4))(2) afforded the pseudo four-coordinate tetrahydroborate complex Mg{HC(C(Me)NAr')(2)}(BH(4))(THF) (1). The corresponding reaction of Ca(BH(4))(2)(THF)(2) or Sr(BH(4))(2)(THF)(2) gave the pseudo five-coordinate analogues M{HC(C(Me)NAr')(2)}(BH(4))(THF)(2) (M = Ca (2) or Sr (3)). All three compounds 1-3 have been structurally characterised. According to X-ray crystallography and IR spectroscopy all possess κ(3)-bound BH(...

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Publication status:
Published

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Publisher copy:
10.1039/c2dt32151c

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
42
Issue:
3
Pages:
759-769
Publication date:
2013-01-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:bd277d90-9f9f-43aa-b301-8fb7e99c4844
Source identifiers:
358299
Local pid:
pubs:358299
Language:
English

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