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A combined experimental/computational study of the mechanism of a palladium-catalyzed bora-Negishi reaction

Abstract:

Experimental and computational efforts are reported which illuminate the mechanism of a novel boron version of the widespread Negishi coupling reaction that offers a new protocol for the formation of aryl/acyl C-B bonds using a bulky boryl fragment. The role of nucleophilic borylzinc reagents in the reduction of the Pd(II) pre-catalysts to Pd(0) active species has been demonstrated. The non-innocent behavior of the PPh3 ligands of the [Pd(PPh3 )2 Cl2 ] pre-catalyst under activation conditions...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1002/chem.201702703

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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Department:
Queens College
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Funding agency for:
Campos, J
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Funding agency for:
Campos, J
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Funding agency for:
Kolychev, EL
Publisher:
Wiley-VCH Verlag Publisher's website
Journal:
Chemistry - A European Journal Journal website
Volume:
23
Issue:
51
Pages:
12655–12667
Publication date:
2017-07-10
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Pubs id:
pubs:708370
URN:
uri:bd03db9d-1e42-41f7-8976-4a337521b001
UUID:
uuid:bd03db9d-1e42-41f7-8976-4a337521b001
Local pid:
pubs:708370

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