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REGIOSPECIFIC AND STEREOSPECIFIC SYNTHESIS OF CIS-(+/-)-1-ACETOXY-4-(ACETOXYMETHYL)CYCLOPENT-2-ENE - A KEY INTERMEDIATE IN THE SYNTHESIS OF CARBOCYCLIC NUCLEOSIDES AND PSEUDO-RIBOFURANOSES

Abstract:
The synthesis of cis-(±)-1-acetoxy-4-(acetoxymethyl)cyclopent-2-ene 1 from cyclopent-3-ene-1-carboxylic acid 2 by way of bromolactonisation, reductive ring opening and diacylation with in situ elimination of HBr is described.
Publication status:
Published

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Publisher copy:
10.1039/p19930001543

Authors


HODGSON, D More by this author
WITHERINGTON, J More by this author
MOLONEY, B More by this author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Issue:
14
Pages:
1543-1544
Publication date:
1993-07-21
DOI:
EISSN:
1364-5463
ISSN:
0300-922X
URN:
uuid:bcbe3b55-6eff-4d5b-8dd7-d82f20208125
Source identifiers:
52152
Local pid:
pubs:52152
Language:
English

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