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PHOTOELECTRON-SPECTRA AND THEIR RELATIVISTIC INTERPRETATION FOR GASEOUS BISMUTH TRIHALIDES

Abstract:
Photoelectron spectra are reported for BiCl3, BiBr3 and BiI3. Assignments are obtained using the relativistically parameterized extended Hückel (REX) and perturbative Hartree-Fock-Slater methods. The halogen p-bands (4a1, 1a2, 4e, and 3e) resemble those in the lighter MX3 molecules at (M = P- Sb). The bismuth-halogen sigma bond MOs (3a1 and 2e) suffer a relativistic rehybridization into e 1 2 > e 3 2 > e 1 2. © 1982.
Publication status:
Published

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Journal:
CHEMICAL PHYSICS
Volume:
72
Issue:
3
Pages:
237-247
Publication date:
1982-01-01
DOI:
ISSN:
0301-0104
URN:
uuid:bbc05df3-f9ee-4ff8-885e-82af85df54bd
Source identifiers:
42173
Local pid:
pubs:42173
Language:
English

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