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Reactivity of the bis(pentafluorophenyl)boranes ClB(C6F5)2 and [HB(C6F5)2]n towards late transition metal reagents.

Abstract:

The reactivities of the highly electrophilic boranes ClB(C(6)F(5))(2) (1) and [HB(C(6)F(5))(2)](n) (2) towards a range of organometallic reagents featuring metals from Groups 7-10 have been investigated. Salt elimination chemistry is observed 1 between and the nucleophilic anions eta(5)-C(5)R(5))Fe(CO)(2)](-)(R = H or Me) and [Mn(CO)(5)](-), leading to the generation of the novel boryl complexes (eta(5)-C(5)R(5))Fe(CO)(2)B(C(6)F(5))(2)[R = H (3) or Me (4)] and (OC)(5)MnB(C(6)F(5))(2) (5). Suc...

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Publication status:
Published

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Publisher copy:
10.1039/b414940h

Authors


Al-Fawaz, A More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Coombs, DL More by this author
Dickinson, AA More by this author
Willock, DJ More by this author
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Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
23
Pages:
4030-4037
Publication date:
2004-12-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:baf2a4a5-b5af-467d-a374-2a7045ff1ccf
Source identifiers:
46037
Local pid:
pubs:46037
Language:
English

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