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Theoretical and experimental aspects of electrodeposition under hydrodynamic conditions

Abstract:

The utility of a recently derived model [M.E. Hyde, O.V. Klymenko, R.G. Compton, J. Electroanal. Chem. 534 (2002) 13] for the potentiostatic nucleation and three dimensional growth of deposits on an electrode surface under hydrodynamic conditions is demonstrated. 2.1 mM Pb2+ solution is used as the depositing species, and a wall-tube and stirred cell are used to generate conditions in which the diffusion layer thickness is in the range 10-40 μm. It is shown that the model provides excellent f...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
581
Issue:
2
Pages:
224-230
Publication date:
2005-08-01
DOI:
ISSN:
0022-0728
URN:
uuid:badb5195-3913-41bb-9082-b1d5eab9d2a4
Source identifiers:
39599
Local pid:
pubs:39599

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