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Harnessing NMR relaxation interference effects to characterise supramolecular assemblies

Abstract:

Solution-state NMR spectroscopy remains the primary method for characterizing synthetic supramolecular assemblies. Yet, in their NMR spectra, relaxation interference effects can significantly alter peak intensities hindering interpretation. Here, we present a simple experiment for synthetic chemists to analyse this effect, allowing interpretion of these distorted spectra and validation of spectral assignments. We apply this experiment to synthetic porphyrin oligomers with molecular weights ap...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/C6CC02544G

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
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Funding agency for:
Anderson, H
Grant:
320969
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Communications Journal website
Volume:
52
Pages:
7450-7453
Publication date:
2016-04-01
Acceptance date:
2016-04-15
DOI:
ISSN:
1364-548X
Source identifiers:
617739
Pubs id:
pubs:617739
UUID:
uuid:ba52a210-92cb-4c4e-a4bf-a913e0719761
Local pid:
pubs:617739
Deposit date:
2016-04-25

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