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Incommensurate chirality density wave transition in a hybrid molecular framework

Abstract:

Using single-crystal x-ray diffraction we characterize the 235 K incommensurate phase transition in the hybrid molecular framework tetraethylammonium silver(I) dicyanoargentate, [NEt4]Ag3(CN)4. We demonstrate the transition to involve spontaneous resolution of chiral [NEt4]+ conformations, giving rise to a state in which molecular chirality is incommensurately modulated throughout the crystal lattice. We refer to this state as an inco...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1103/physrevlett.119.115501

Authors


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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
St Annes College
Engineering and Physical Sciences Research Council More from this funder
Publisher:
American Physical Society Publisher's website
Journal:
Physical review letters Journal website
Volume:
119
Issue:
11
Pages:
115501
Publication date:
2017-09-14
DOI:
EISSN:
1079-7114
ISSN:
0031-9007
Pubs id:
pubs:733004
URN:
uri:ba330be4-729d-4e25-b3ed-9c005315d0eb
UUID:
uuid:ba330be4-729d-4e25-b3ed-9c005315d0eb
Local pid:
pubs:733004
Language:
English
Keywords:

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