- Abstract:
-
Using single-crystal x-ray diffraction we characterize the 235 K incommensurate phase transition in the hybrid molecular framework tetraethylammonium silver(I) dicyanoargentate, [NEt4]Ag3(CN)4. We demonstrate the transition to involve spontaneous resolution of chiral [NEt4]+ conformations, giving rise to a state in which molecular chirality is incommensurately modulated throughout the crystal lattice. We refer to this state as an inco...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted manuscript
- Files:
-
-
(pdf, 963.7kb)
-
- Publisher copy:
- 10.1103/physrevlett.119.115501
-
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- Publisher:
- American Physical Society Publisher's website
- Journal:
- Physical review letters Journal website
- Volume:
- 119
- Issue:
- 11
- Pages:
- 115501
- Publication date:
- 2017-09-14
- DOI:
- EISSN:
-
1079-7114
- ISSN:
-
0031-9007
- Pubs id:
-
pubs:733004
- URN:
-
uri:ba330be4-729d-4e25-b3ed-9c005315d0eb
- UUID:
-
uuid:ba330be4-729d-4e25-b3ed-9c005315d0eb
- Local pid:
- pubs:733004
- Language:
- English
- Keywords:
- Copyright holder:
- American Physical Society
- Copyright date:
- 2017
- Notes:
-
This is the author accepted manuscript following peer review version of the article. The final version is
available online from American Physical Society at: https://doi.org/10.1103/PhysRevLett.119.115501
Journal article
Incommensurate chirality density wave transition in a hybrid molecular framework
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