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A new phosphine-functionalised [1] ferrocenophane and its use in the functionalisation of mesoporous silicas

Abstract:

The permethylated phosphine-functionalised cyclopentadienyl ligand system, Li2[Me2Si(2,3,4-Me3-5-PPh2C 5)2], has been prepared starting from 1,2,3- trimethylcyclopentadiene. This ligand has been employed to prepare the novel bis(diphenyl)phosphine-functionalised silyl-bridged [1]ferrocenophane, rac-Fe[Me2Si(2,3,4-Me3-5-PPh2C 5)2]. Reaction of rac-Fe[Me2Si(2,3,4-Me 3-5-PPh2C5)2] with the mesoporous silicas MCM-41, MCM-48, SBA-15 leads to ring opening of the ansa-bridge and the immobilisation o...

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Publication status:
Published

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Publisher copy:
10.1039/b513133b

Authors


Miller, CJ More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
JOURNAL OF MATERIALS CHEMISTRY
Volume:
15
Issue:
47
Pages:
5070-5080
Publication date:
2005
DOI:
EISSN:
1364-5501
ISSN:
0959-9428
URN:
uuid:b98d2840-2251-4513-9a68-23f4c78ebcc7
Source identifiers:
51310
Local pid:
pubs:51310
Language:
English

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