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Aqueous voltammetry in the near absence of electrolyte

Abstract:

In order to minimize the incidence of the CO2 hydrolysis and conduct aqueous electrochemistry in the virtual absence of electrolyte, a novel methodology is developed to achieve the near minimum conductivity (≈60 nS cm−1) for an aqueous solution through in situ deionization with ion exchange resin beads. Aqueous electrochemistry studying the oxidations of platinum, ferrocenemethanol, and hydrogen (H2) were conducted in the near complete absence of trace ionic species at a platinum microelectro...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1002/chem.201703525

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Department:
Oxford, MPLS, Chemistry, Physical & Theoretical Chem
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Department:
Oxford, MPLS, Chemistry, Physical & Theoretical Chem
Laborda, E More by this author
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Department:
St Johns College
Publisher:
Wiley‐VCH Verlag Publisher's website
Journal:
Chemistry - A European Journal Journal website
Volume:
23
Issue:
60
Pages:
15222-15226
Publication date:
2017-10-06
Acceptance date:
2017-09-06
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Pubs id:
pubs:725947
URN:
uri:b9385c21-bf00-470f-beac-bfbb998ecaa7
UUID:
uuid:b9385c21-bf00-470f-beac-bfbb998ecaa7
Local pid:
pubs:725947

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