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Microwave activation of electrochemical processes: Square-wave voltammetric stripping detection of cadmium in the presence of the surfactant triton X

Abstract:

A novel electrochemical cell based on a flow through system in a microwave cavity is shown to allow voltammetnc experiments under microwave conditions. Focusing of the microwave radiation at the electrode-solution (electrolyte) interface creates conditions of extreme localized heating with an inverted thermal gradient within the diffusion layer of the electrode and convective flow. The deposition and anodic stripping detection by square-wave voltammetry of Cd2+ in a 0.1 M acetate buffer solut...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
ELECTROANALYSIS
Volume:
13
Issue:
8-9
Pages:
639-645
Publication date:
2001-05-05
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
URN:
uuid:b9372b52-f48a-481e-9dbd-c499ebaf8c98
Source identifiers:
37837
Local pid:
pubs:37837

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