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Copper(II)-directed synthesis of neutral heteroditopic [2]rotaxane ion-pair host systems incorporating hydrogen and halogen bonding anion binding cavities

Abstract:

Neutral heteroditopic [2]rotaxane ion-pair host systems were synthesised via a Cu(II) directed passive metal template strategy. Each rotaxane contains discrete, axle-separated interlocked binding sites for a guest anion and a transition metal countercation. The anion binding sites are composed of convergent X–H (X = C, N) hydrogen bond donor groups, or mixed X–H and C–I hydrogen and halogen bond donor groups, whereas an equivalent three-dimensional array of amine, pyridine and carbonyl oxygen...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1039/C7DT02832F

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Department:
Oxford, MPLS, Chemistry, Organic Chemistry
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Author
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Department:
Oxford, MPLS, Chemistry, Organic Chemistry
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Author
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Department:
Oxford, MPLS, Chemistry, Organic Chemistry
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Author
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Department:
Wadham College
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Author
University of Oxford More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Dalton Transactions Journal website
Volume:
46
Issue:
39
Pages:
13376-13385
Publication date:
2017-09-27
Acceptance date:
2017-09-12
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
Pubs id:
pubs:731241
URN:
uri:b9098c00-e100-4590-9346-895eccaef0cc
UUID:
uuid:b9098c00-e100-4590-9346-895eccaef0cc
Local pid:
pubs:731241

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