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Zirconium complexes of diamine-bis(phenolate) ligands: Synthesis, structures, and solution dynamics

Abstract:
A study was performed on the synthesis, structures and solution dynamics of zirconium complexes of diamine-bis(phenolate) ligands. A series of six- or eight-coordinate derivatives were prepared and crystallographically characterized. It was found that attempts to generate catalytically active systems for the polymerization of ethylene were unsuccessful, although THF-stabilized benzyl cations were identified.
Publication status:
Published

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Publisher copy:
10.1021/om010982w

Authors


Toupance, T More by this author
Dubberley, SR More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Tyrrell, BR More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
ORGANOMETALLICS
Volume:
21
Issue:
7
Pages:
1367-1382
Publication date:
2002-04-01
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:b877dcd1-2418-4db3-879e-8a31d00a1f29
Source identifiers:
51235
Local pid:
pubs:51235
Language:
English

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