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Chiral Phosphine-Phosphite Ligands with a Substituted Ethane Backbone. Influence of Conformational Effects in Rhodium-Catalyzed Asymmetric Olefin Hydrogenation and Hydroformylation Reactions

Abstract:: A family of chiral (3,3′-di-tert-butyl-5,5′,6,6′- tetramethyl-2,2′-biphenol-derived) phosphine-phosphite ligands (P-OP) with a substituted ethane backbone has been synthesized and the performance of these ligands in the Rh-catalyzed enantioselective hydrogenation and hydroformylation of several representative olefins analyzed. Corresponding cationic rhodium complexes provide highly enantioselective catalysts for the hydrogenation of methyl (Z)-α-acetamidocinnamate (MAC) and dimethyl itaconate...
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Publication status:: Published

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APA Style

Arribas, I., Vargas, S., Rubio, M., Suarez, A., Domene, C., Alvarez, E., & Pizzano, A. (2010). Chiral Phosphine-Phosphite Ligands with a Substituted Ethane Backbone. Influence of Conformational Effects in Rhodium-Catalyzed Asymmetric Olefin Hydrogenation and Hydroformylation Reactions. ORGANOMETALLICS, 29(22), 5791–5804.

MLA Style

Arribas, I., et al. “Chiral Phosphine-Phosphite Ligands with a Substituted Ethane Backbone. Influence of Conformational Effects in Rhodium-Catalyzed Asymmetric Olefin Hydrogenation and Hydroformylation Reactions.” ORGANOMETALLICS, vol. 29, no. 22, 2010, pp. 5791–804.

Chicago Style

Arribas, I, S Vargas, M Rubio, A Suarez, C Domene, E Alvarez, and A Pizzano. 2010. “Chiral Phosphine-Phosphite Ligands with a Substituted Ethane Backbone. Influence of Conformational Effects in Rhodium-Catalyzed Asymmetric Olefin Hydrogenation and Hydroformylation Reactions.” ORGANOMETALLICS 29 (22): 5791–5804.
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Publisher copy:: 10.1021/om1003545

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+ Vargas, S More by this author

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+ Rubio, M More by this author

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+ Domene, C More by this author

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Bibliographic Details

Journal:: ORGANOMETALLICS
Volume:: 29
Issue:: 22
Pages:: 5791-5804
Publication date:: 2010-11-22
DOI:: 10.1021/om1003545
EISSN:: 1520-6041
ISSN:: 0276-7333

Item Description

Language:: English
Pubs id:: pubs:118292
UUID:: uuid:b85a6e79-dc69-40b6-af9d-326b681e3b01
Local pid:: pubs:118292
Source identifiers:: 118292
Deposit date:: 2012-12-19

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Copyright date:: 2010

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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