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Transmembrane anion transport mediated by halogen bonding and hydrogen bonding triazole anionophores

Abstract:

Transmembrane ion transport by synthetic anionophores is typically achieved using polar hydrogen bonding anion receptors. Here we show that readily accessible halogen and hydrogen bonding 1,2,3-triazole derivatives can efficiently mediate anion transport across lipid bilayer membranes with unusual anti-Hofmeister selectivity. Importantly, the results demonstrate that the iodo-triazole systems exhibit the highest reported activity to date for halogen bonding anionophores, and enhanced transpor...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/D0SC01467B

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
ORCID:
0000-0002-6062-8209
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
ORCID:
0000-0003-1555-3479
More from this funder
Name:
Royal Society
Grant:
URF\R1\180176
Publisher:
Royal Society of Chemistry
Journal:
Chemical Science More from this journal
Volume:
11
Issue:
18
Pages:
4722-4729
Publication date:
2020-04-15
Acceptance date:
2020-04-14
DOI:
EISSN:
2041-6539
ISSN:
2041-6520
Language:
English
Keywords:
Pubs id:
1100242
Local pid:
pubs:1100242
Deposit date:
2020-04-15

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