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Palladium catalyzed tandem alkenyl- and aryl-C-N bond formation: a cascade N-annulation route to 4-, 5-, 6-and 7-chloroindoles

Abstract:
A series of trihalogenated alkenylbenzenes undergo consecutive palladium catalyzed inter- and intramolecular amination reactions to deliver a series of 1-functionalized mono-chloroindoles. 4-, 5-, 6- and 7-Chloroindoles can all be prepared; carbamates, anilines and amines can be employed as the N-nucleophile. © 2010 Elsevier Ltd.
Publication status:
Published

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Publisher copy:
10.1016/j.tet.2010.05.046
Host title:
TETRAHEDRON
Volume:
66
Issue:
33
Pages:
6632-6638
Publication date:
2010-08-14
DOI:
ISSN:
0040-4020
Keywords:
Pubs id:
pubs:67558
UUID:
uuid:b83659cb-963e-4526-9cd2-3b9625cc490a
Local pid:
pubs:67558
Source identifiers:
67558
Deposit date:
2012-12-19

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