Journal article
THE PHOTO-CE MECHANISM - THE OXIDATION OF TRIS-(PARA-TOLYL)AMINE IN ACETONITRILE AT AN ILLUMINATED PLATINUM-ELECTRODE
- Abstract:
-
The oxidation of tris-(p-tolyl)amine (A) has been studied in acetonitrile solution using a channel electrode flow cell. In the dark a simple reversible one-electron oxidation to the corresponding (stable) radical cation is observed. However on irradiation with light of wavelength 300 nm a 'pre-wave' is additionally seen ca. 200 mV cathodic of the simple 'dark' process. Action spectrum measurements, preparative experiments and photocurrent/solution flow rate data are used to show that this pro...
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- Publication status:
- Published
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- Publisher copy:
- 10.1039/ft9908603603
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Bibliographic Details
- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS
- Volume:
- 86
- Issue:
- 21
- Pages:
- 3603-3606
- Publication date:
- 1990-11-07
- DOI:
- EISSN:
-
1364-5455
- ISSN:
-
0956-5000
- Source identifiers:
-
43430
Item Description
- Language:
- English
- Pubs id:
-
pubs:43430
- UUID:
-
uuid:b7ef674d-5bd4-44a0-9912-a5422090aa2d
- Local pid:
- pubs:43430
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 1990
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