- Abstract:
-
Conjugated polyrotaxanes jacketed with hole-transport groups have been synthesized from water-soluble polyrotaxanes consisting of a polyfluorene-alt-biphenylene (PFBP) conjugated polymer threaded through β-cyclodextrin macrocycles. The hydroxyl groups of the oligosaccharides were efficiently functionalized with triphenylamine (TPA) so that every polyrotaxane molecule carries a coat of about 200 TPA units, forming a supramolecular coaxial structure. This architecture was characterized using a ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/jp500624q
-
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- Journal:
- JOURNAL OF PHYSICAL CHEMISTRY C
- Volume:
- 118
- Issue:
- 8
- Pages:
- 4553-4566
- Publication date:
- 2014-02-27
- DOI:
- EISSN:
-
1932-7455
- ISSN:
-
1932-7447
- URN:
-
uuid:b7b31051-c877-4dcc-936e-7f3790c1e1e7
- Source identifiers:
-
459742
- Local pid:
- pubs:459742
- Language:
- English
- Copyright date:
- 2014
Journal article
Synthesis and Photophysics of Coaxial Threaded Molecular Wires: Polyrotaxanes with Triarylamine Jackets
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