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Group 6 imido complexes supported by diamido-donor ligands.

Abstract:

Reactions of the lithiated diamido-pyridine or diamido-amine ligands Li(2)N(2)N(py) or Li(2)N(2)N(am) with [W(NAr)Cl(4)(THF)] (Ar = Ph or 2,6-C(6)H(3)Me(2); THF = tetrahydrofuran) afforded the corresponding imido-dichloride complexes [W(NAr)(N(2)N(py))Cl(2)] (R = Ph, 1, or 2,6-C(6)H(3)Me(2), 2) or [W(NAr)(N(2)N(am))Cl(2)] (R = Ph, 3, or 2,6-C(6)H(3)Me(2), 4), respectively, where N(2)N(py) = MeC(2-C(5)H(4)N)(CH(2)NSiMe(3))(2) and N(2)N(am) = Me(3)SiN(CH(2)CH(2)NSiMe(3))(2). Subsequent reaction...

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Publication status:
Published

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Publisher copy:
10.1021/ic034377s

Authors


Dubberley, SR More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Inorganic chemistry
Volume:
42
Issue:
16
Pages:
4961-4969
Publication date:
2003-08-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:b702925d-ac04-4254-8b4d-071ed36333b1
Source identifiers:
51034
Local pid:
pubs:51034
Language:
English

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