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Importance of halogen···halogen contacts for the structural and magnetic properties of CuX2(pyrazine-N,N′-dioxide)(H2O)2 (X = Cl and Br).

Abstract:

The structural and magnetic properties of the newly crystallized CuX(2)(pyzO)(H(2)O)(2) (X = Cl, Br; pyzO = pyrazine-N,N'-dioxide) coordination polymers are reported. These isostructural compounds crystallize in the monoclinic space group C2/c with, at 150 K, a = 17.0515(7) Å, b = 5.5560(2) Å, c = 10.4254(5) Å, β = 115.400(2)°, and V = 892.21(7) Å(3) for X = Cl and a = 17.3457(8) Å, b = 5.6766(3) Å, c = 10.6979(5) Å, β = 115.593(2)°, and V = 950.01(8) Å(3) for X = Br. Their crystal structure...

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Publication status:
Published

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Publisher copy:
10.1021/ic201924q

Authors


Schlueter, JA More by this author
Halder, GJ More by this author
Armand, WR More by this author
Dunmars, C More by this author
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Journal:
Inorganic chemistry
Volume:
51
Issue:
4
Pages:
2121-2129
Publication date:
2012-02-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:b6e57702-194a-4898-b1d4-754ba2ff7523
Source identifiers:
245903
Local pid:
pubs:245903
Language:
English

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