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Emulsion electrosynthesis in the presence of power ultrasound Biphasic Kolbe coupling processes at platinum and boron-doped diamond electrodes

Abstract:

The electrochemical oxidation of aliphatic carboxylic acids, hexanoic, heptanoic, and lauric acid, under biphasic conditions is studied as a model system for ultrasound enhanced Kolbe electrosynthesis processes. Power ultrasound is used to generate an in situ emulsified medium and to remove reaction products continuously from the electrode surface. A clean and highly efficient process at platinum electrodes with formation of 'one electron' products only occurs in marked contrast to processes ...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY More from this journal
Volume:
507
Issue:
1-2
Pages:
135-143
Publication date:
2001-07-13
DOI:
ISSN:
0022-0728
Language:
English
Keywords:
Pubs id:
pubs:37931
UUID:
uuid:b6bce3dc-0d88-487b-af40-2f015930b938
Local pid:
pubs:37931
Source identifiers:
37931
Deposit date:
2012-12-19

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