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Journal article

Structural chemistry and metamagnetism of an homologous series of layered manganese oxysulfides.

Abstract:

An homologous series of layered oxysulfides Sr2MnO2Cu(2m-delta)S(m+1) with metamagnetic properties is described. Sr2MnO2Cu(2-delta)S2 (m = 1), Sr2MnO2Cu(4-delta)S3 (m = 2) and Sr2MnO2Cu(6-delta)S4 (m = 3), consist of MnO2 sheets separated from antifluorite-type copper sulfide layers of variable thickness by Sr(2+) ions. All three compounds show substantial and similar copper deficiencies (delta approximately equal to 0.5) in the copper sulfide layers, and single-crystal X-ray and powder neutr...

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Publication status:
Published

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Publisher copy:
10.1021/ja060892o

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Journal:
Journal of the American Chemical Society
Volume:
128
Issue:
26
Pages:
8530-8540
Publication date:
2006-07-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Source identifiers:
33518
Language:
English
Pubs id:
pubs:33518
UUID:
uuid:b6b4fb47-82cc-4965-beb8-b80454e75311
Local pid:
pubs:33518
Deposit date:
2012-12-19

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