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[Rh(7)(PiPr(3))(6)H(18)][BAr(F) (4)](2): a molecular Rh(111) surface decorated with 18 hydrogen atoms.

Abstract:
Heptarhodium wagon wheel [Rh7(PiPr3) 6H18][BArF4]2 (shown), which resembles a planar Rh(111) surface with 18 hydride ligands, was obtained together with [Rh8(PiPr3)6H16] [BArF4]2 from the reaction of [Rh(PiPr 3)2(nbd)][BArF4] and [Rh(nbd) 2][BArF4] with hydrogen (ArF = C6H3(CF3)2, nbd = norbornadiene). Some of the H ligands are located in threefold hollows between Rh centers and thus mimic the orientation of atomic hydrogen adsorbed on Rh(111). (Figure Presented). © 2007 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200703069

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Journal:
Angewandte Chemie (International ed. in English)
Volume:
46
Issue:
41
Pages:
7844-7848
Publication date:
2007-01-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Source identifiers:
40529
Language:
English
Keywords:
Pubs id:
pubs:40529
UUID:
uuid:b67f9a1d-74ec-4f07-94dc-eeadc75936fb
Local pid:
pubs:40529
Deposit date:
2012-12-19

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