Journal article
[Rh(7)(PiPr(3))(6)H(18)][BAr(F) (4)](2): a molecular Rh(111) surface decorated with 18 hydrogen atoms.
- Abstract:
- Heptarhodium wagon wheel [Rh7(PiPr3) 6H18][BArF4]2 (shown), which resembles a planar Rh(111) surface with 18 hydride ligands, was obtained together with [Rh8(PiPr3)6H16] [BArF4]2 from the reaction of [Rh(PiPr 3)2(nbd)][BArF4] and [Rh(nbd) 2][BArF4] with hydrogen (ArF = C6H3(CF3)2, nbd = norbornadiene). Some of the H ligands are located in threefold hollows between Rh centers and thus mimic the orientation of atomic hydrogen adsorbed on Rh(111). (Figure Presented). © 2007 Wiley-VCH Verlag GmbH and Co. KGaA.
- Publication status:
- Published
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- Publisher copy:
- 10.1002/anie.200703069
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Bibliographic Details
- Journal:
- Angewandte Chemie (International ed. in English)
- Volume:
- 46
- Issue:
- 41
- Pages:
- 7844-7848
- Publication date:
- 2007-01-01
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Source identifiers:
-
40529
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:40529
- UUID:
-
uuid:b67f9a1d-74ec-4f07-94dc-eeadc75936fb
- Local pid:
- pubs:40529
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2007
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