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High-utilisation nanoplatinum catalyst (Pt@cPIM) obtained via vacuum carbonisation in a molecularly rigid polymer of intrinsic microporosity

Abstract:

Polymers of intrinsic microporosity (PIM or here PIM-EA-TB) offer a highly rigid host environment into which hexachloroplatinate(IV) anions are readily adsorbed and vacuum carbonised (at 500 °C) to form active embedded platinum nanoparticles. This process is characterised by electron and optical microscopy, atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and electrochemical methods, which reveal that the PIM microporosity facilitates the assembly of nanoparticles of typi...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1007/s12678-016-0347-5

Authors


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University of Bath More from this funder
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Grant:
Newton International Fellowship
Publisher:
Springer Publisher's website
Journal:
Electrocatalysis Journal website
Volume:
8
Issue:
2
Pages:
132-143
Publication date:
2016-12-05
Acceptance date:
2016-12-01
DOI:
ISSN:
1868-2529 and 1868-5994
Pubs id:
pubs:686035
URN:
uri:b6486082-fc36-43e5-a1e0-e82ab5efd22b
UUID:
uuid:b6486082-fc36-43e5-a1e0-e82ab5efd22b
Local pid:
pubs:686035

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