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Journal article

Single-molecule imaging and kinetic analysis of intermolecular polyoxometalate reactions

Abstract:

We induce and study reactions of polyoxometalate (POM) molecules, [PW12O40]3− (Keggin) and [P2W18O62]6− (Wells–Dawson), at the single-molecule level. Several identical carbon nanotubes aligned side by side within a bundle provided a platform for spatiotemporally resolved imaging of ca. 100 molecules encapsulated within the nanotubes by transmission electron microscopy (TEM). Due to the entrapment of POM molecules their proximity to one another is effectively controlled, limiting molecular mot...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/d1sc01874d

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
ORCID:
0000-0002-6353-6000
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Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Science Journal website
Volume:
12
Issue:
21
Pages:
7377-7387
Publication date:
2021-04-26
Acceptance date:
2021-04-12
DOI:
EISSN:
2041-6539
ISSN:
2041-6520
Language:
English
Keywords:
Pubs id:
1175895
Local pid:
pubs:1175895
Deposit date:
2021-06-15

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