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Structural diversity and luminescent properties of lanthanide 2,2- and 2,3-dimethylsuccinate frameworks

Abstract:

The structures of fourteen new lanthanide frameworks (La, Ce, Eu, Tb, Y and Lu) containing the 2,2- or 2,3-dimethylsuccinate ligands are reported. While the majority of the known 2,2-dimethylsuccinate frameworks feature two dimensionally bonded layers, capped by hydrophobic methyl groups, several of these new frameworks adopt quite different architectures. These include one dimensional inorganically connected chains (La and Ce) with only non-covalent interactions in the other two dimensions, ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c2ce26279g

Authors


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Institution:
University of Oxford
Role:
Author
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Institution:
University of Oxford
Division:
MPLS
Department:
Engineering Science
Role:
Author
European Research Council More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
CrystEngComm Journal website
Volume:
15
Issue:
1
Pages:
100-110
Publication date:
2012-09-19
Acceptance date:
2012-09-18
DOI:
EISSN:
1466-8033
ISSN:
1466-8033
Source identifiers:
367247
Pubs id:
pubs:367247
UUID:
uuid:b5ec5e50-7c12-40c1-8579-1f44a6ed2705
Local pid:
pubs:367247
Deposit date:
2013-11-16

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