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Analytical theory of the catalytic mechanism in square wave voltammetry at disc electrodes.

Abstract:

A simple analytical expression is presented for the study of the first-order catalytic mechanism using Square Wave Voltammetry (SWV) at disc electrodes. These electrodes are extensively used in electrochemical studies but modelling the electrochemical response at this geometry is complex and usually requires the use of sophisticated numerical methods. By contrast, the analytical solution presented in this work is easy to compute and it is applicable to any size of the disc and for arbitrary k...

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Publication status:
Published

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Publisher copy:
10.1039/c1cp22032b

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
13
Issue:
37
Pages:
16748-16755
Publication date:
2011-10-01
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Source identifiers:
172068
Language:
English
Pubs id:
pubs:172068
UUID:
uuid:b5e36b5d-7d07-4753-8ac3-7cd2faa871de
Local pid:
pubs:172068
Deposit date:
2012-12-19

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