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[(iPr3P)6Rh6H12]2+: a high-hydride content octahedron that bridges the gap between late and early transition metal clusters.

Abstract:

Treatment of [(iPr3P)2Rh(nbd)][Y] {nbd = norbornadiene, Y = B{3,5-(CF3)2C6H3}4- [B(ArF)4] or 1-H-closo-CB11Me11-} with H2 (ca. 4 atm) results in the isolation, in moderate yield, of the octahedral cluster complex [(iPr3P)6Rh6H12][Y]2 1. The cluster (for both anions) has been characterized by NMR, mass spectroscopy, and X-ray crystallography. These show 1 to have 12 edge-bridging hydrogen atoms, and the structure bears more resemblance to clusters of the early transition metals with pi-donor l...

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Publication status:
Published

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Publisher copy:
10.1021/ja049402n

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Journal of the American Chemical Society More from this journal
Volume:
126
Issue:
15
Pages:
4784-4785
Publication date:
2004-04-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
Pubs id:
pubs:51687
UUID:
uuid:b5bffdee-da98-4bdd-8190-7e3f2fd28adf
Local pid:
pubs:51687
Source identifiers:
51687
Deposit date:
2012-12-19

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