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Underpotential deposition of lithium on platinum single crystal electrodes in tetrahydrofuran

Abstract:

We present the first electrochemical observation/studies of nucleation and underpotential deposition (upd) of lithium in tetrahydrofuran (THF) on platinum single crystals. Electrochemical data using platinum (100) [Ep,c = -3.3 V, and Ep,a = -2.6 V], (110) [Ep,c = -3.0 V, and Ep,a = -2.2 V], and (111) [Ep,c = -1.6 V, and E p,a = -1.3 V] single crystal electrodes are reported against a standard reference electrode, Fc/Fc+PF6- for use in THF. The study has shown that lithium upd occurs at differ...

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Publication status:
Published

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Publisher copy:
10.1021/jp073304h

Authors


Paddon, CA More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF PHYSICAL CHEMISTRY C
Volume:
111
Issue:
26
Pages:
9016-9018
Publication date:
2007-07-05
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
URN:
uuid:b5b29b42-ae0a-41b3-9587-d4056244004f
Source identifiers:
40359
Local pid:
pubs:40359
Language:
English

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