- Abstract:
-
The electrocatalytic reactions of vitamin B12s with three vicinal dibromides (cis-1,2-dibromocyclohexane, trans-1,2-dibromocyclohexane and 1,2-dibromobutane) are investigated in homogeneous and heterogeneous media. In the latter, cyclic voltammetry with basal plane pyrolytic graphite electrodes modified with microdroplets of dodecane+dibromide is employed to obtain kinetic parameters for the liquid/liquid reaction. The homogeneous and interfacial reactions exhibit marked differences in reacti...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/j.jelechem.2004.03.028
-
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- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 570
- Issue:
- 2
- Pages:
- 171-185
- Publication date:
- 2004-09-01
- DOI:
- ISSN:
-
0022-0728
- URN:
-
uuid:b59b0291-a596-40f2-bdf4-23f1a59c7c9c
- Source identifiers:
-
39254
- Local pid:
- pubs:39254
- Language:
- English
- Keywords:
- Copyright date:
- 2004
Journal article
Cyclic voltammetry at microdroplet modified electrodes. A comparison of the reaction of vicinal dibromides with vitamin B-12s at the liquid/liquid interface with the corresponding homogeneous process: evidence for polar-solvent effects at the liquid/liquid interface
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