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Radical translocation reactions in synthesis

Abstract:
This review highlights synthetically useful transformations of organic free-radicals in which a key step is relocation of the radical site by intramolecular abstraction either of a hydrogen atom or a group (e.g. phenyl, cyano, trialkylsilyl). The material is organised around the nature of the radical that initiates translocation and coverage is largely confined to reports that have appeared within the past decade, reference to earlier work only being made in order to establish a context for more recent results.
Publication status:
Published

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Publisher copy:
10.1039/b000705f

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Journal:
CHEMICAL SOCIETY REVIEWS
Volume:
30
Issue:
2
Pages:
94-103
Publication date:
2001-03-05
DOI:
EISSN:
1460-4744
ISSN:
0306-0012
URN:
uuid:b571d35a-fecb-438a-90e9-bff62cb59a06
Source identifiers:
55235
Local pid:
pubs:55235
Language:
English

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