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Thesis

New main group and rare earth complexes and their applications in the ring-opening polymerisation of cyclic esters

Abstract:

This Thesis describes the synthesis and characterisation of new Main Group and Rare Earth alkyl, amide, alkoxide and borohydride complexes and their use as catalysts for the ring-opening polymerisation (ROP) of ε-caprolactone and rac-lactide.

Chapter 1 introduces ROP from an industrial and academic perspective, as well as polymer characterisation techniques. A literature review is given, with an emphasis placed on Main Group catalysts.

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Institution:
University of Oxford
Research group:
Prof. Philip Mountford
Oxford college:
Merton College
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author

Contributors

Role:
Supervisor
Publication date:
2011
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
Oxford University, UK
URN:
uuid:b5041775-575f-46bb-9f52-dc3417e76cca
Local pid:
ora:12134

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